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中国物理学会期刊

采用NdBCO/MgO籽晶的楼层式批量化制备YBCO超导块材

Batch fabrication of YBCO bulk superconductors via a stacked architecture using NdBCO/MgO seeds

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  • REBCO高温超导块材性能卓越、前景广阔,但制造成本阻碍其工业化应用,现有批量化制备方式在产能和成本上有很大优化空间.基于此,本研究聚焦工艺创新以降本增效,推动其产业化应用.研究采用TSIG法制备NdBCO/MgO自供给籽晶.经MgO掺杂将籽晶熔点从1090.5℃提升至1102.3℃,自然解理获得高熔点复合籽晶.研究结合籽晶熔融织构法(SMG)、“楼层式”结构及固相包裹籽晶技术实现YBCO超导块材高效批量化制备.同时,通过SEM观测样品微观形貌,揭示了“楼层式”结构对YBCO超导块材性能的影响机制.所制备的三层直径28 mm样品(S1、S2、S3),平均最大捕获磁场(Bmax)分别为0.35 T、0.39 T、0.40 T (77 K,0.5 T),捕获磁场率超76%,平均最大磁悬浮力(Fmax)分别为62.5 N、73.2 N、75.5 N (77 K,0.5 T),保持了优异性能.本研究创新性提出的“楼层式”结构,在保障YBCO块材高性能的同时,显著提升制备效率,为其低成本工业化应用提供了有效技术路径.

    REBCO high-temperature bulk superconductors demonstrate exceptional performance but face industrialization barriers due to high manufacturing costs. Current batch production methods require optimization of production capacity and cost-effectiveness. This study innovates processes to reduce costs and enhance efficiency for REBCO industrialization. NdBCO/MgO seeds were prepared by the top seed melt infiltration growth (TSIG) method, systematically investigating the doping effects of MgO within the Nd211 + 0.2BaCuO2 + 1 wt% CeO2 + x wt% MgO system. The results identified an optimal MgO doping content of 16 wt%, which effectively raised the seed melting point by 11.8 °C to 1102.3 °C. Through natural cleavage, high-melting-point NdBCO/MgO seeds were obtained. By integrating the seeded melt growth (SMG) technique with the innovative “stacked architecture” design, efficient batch production of YBCO superconductors was achieved. Additionally, the solid-phase seed wrapping technique was implemented to relax the stringent requirements for seed, enabling more flexible processing conditions. Performance characterization of YBCO samples showed that for triple-layer samples (28 mm diameter, S1/S2/S3) prepared by the stacked architecture, the average maximum trapped magnetic field (Bmtr) values were 0. 35 T, 0. 39 T, and 0. 40 T, respectively, with an average trapped field ratio exceeding 76%; the average maximum levitation forces (Fmax) were 62.5 N, 73.2 N, and 75.5 N. The study utilized SEM to observe the micro-morphology, revealing the influence mechanism of the “stacked architecture” on sample performance. In conclusion, the innovative stacked architecture for batch fabrication of YBCO bulk superconductors significantly improves production efficiency while maintaining high performance.

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