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中国物理学会期刊

YAG晶体的高温拉伸及缺陷演变

Various-temperature tensile and defect evolution of YAG crystal

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  • YAG晶体是重要的激光基质材料,研究原子尺度下YAG的应力、应变及缺陷产生机理对高质量大尺寸晶体生长具有重要意义。运用分子动力学方法模拟了111、110、100晶向在不同温度下的拉伸力学性质和缺陷结构演变。发现YAG呈典型的脆性材料特征,随应变增加,在1300K温度以下,YAG先经历弹性形变,随即断裂,在1800K后,先经历弹性形变,呈现一非常狭窄的塑性形变区域,然后断裂,在2200K时,晶体塑性增强,经历弹性和塑性形变,不易断裂。常温下110弹性模量最大,100弹性模量最小,随着温度的升高弹性模量显著下降,力学各向异性减弱或消失。根据应变应力曲线,给出了YAG断裂应变、极限应力值和断裂能随温度变化的经验公式。在拉伸形变下,YAG晶体会形成微孔、微裂纹等缺陷,升高温度后更容易发生晶格滑移,形成位错与层错缺陷。

    Yttrium aluminum garnet (YAG) crystal is an important laser matrix material. Its atomic-scale mechanical characteristics and defect generation mechanism are of great significance for the growth of high-quality large-size crystals. In this study, the tensile mechanical properties, energy property and defect structure evolution mechanism of 111, 110 and 100 crystal orientations at 300~2200 K were revealed by molecular dynamics simulation. It is found that YAG exhibits typical brittle material characteristics at room temperature. The mechanical properties of YAG crystal are anisotropic. The simulation confirms that the elastic modulus of YAG has a significant strain scale effect. When the strain is less than 0.02, the order of elastic modulus is 100 > 110 > 111.When the strain exceeds 0.05, 100 orientation has the largest decrease in elastic modulus, and the order changes to 110 > 111 > 100. This phenomenon was verified by nanoindentation experiments, indicating that the 110 crystal orientation has the highest tensile strength. The simulation results also show that the mechanical properties of YAG are significantly affected by temperature. It shows typical brittle fracture characteristics below 1300 K, and a very narrow plastic deformation zone appears at 1800 K. It shows continuous plastic deformation ability after reaching 6 GPa yield stress at 2200 K. As the temperature increases, the elastic modulus decreases, and the mechanical anisotropy weakens or disappears. According to the strain-stress curve, the empirical formulas of YAG fracture strain, ultimate stress value and fracture energy changing with temperature are given. The defect evolution characteristics of YAG at different temperatures are also different. Under tensile deformation, YAG crystals will form defects such as micropores and microcracks. After increasing the temperature, lattice slip is more likely to occur, forming dislocations and stacking faults. Near the melting point, plastic deformation is likely to occur to produce a large range of disordered glassy structure. This study provides an atomic scale theoretical basis for the optimization of YAG crystal growth process. This has guiding significance for the preparation of large size and high quality YAG crystal optical elements.

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