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基于氙灯的非相干宽带腔增强吸收光谱系统, 并将其应用于痕量气体及气溶胶消光系数的测量. 该系统的探测灵敏度通过测量NO2在520560 nm波长范围内的吸收得到验证, 最小可探测灵敏度为1.8 10-7cm-1 (1, 0.12 s积分时间, 50次平均), 对应的NO2探测极限~33 nmol/mol. 结合标准气溶胶粒子发生系统, 测量了不同浓度的单分散硫酸铵气溶胶粒子在532 nm波长处的消光系数, 得到粒径为600 nm的硫酸铵气溶胶的消光截面为1.12 10-8cm2, 与文献报道值1.167 10-8cm2相一致, 验证了气溶胶测量的可行性和准确性.
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关键词:
- 宽带腔增强吸收光谱技术/
- 痕量气体探测/
- 气溶胶光学特性
We report on the development of incoherent broadband cavity enhanced absorption spectroscopy system based on a short arc Xenon lamp for trace gas detection and aerosol optical properties measurements. A minimum detection sensitivity of 1.8 10-7cm-1 (1, 0.12 s integrating time, and 50 times average) is obtained on the basis of absorption spectroscopy of NO2 in a spectral range of 520560 nm, which corresponds to a minimum detection concentration of ~33 nmol/mol for NO2. Combining a laboratory aerosol generation system, the extinction coefficients of 600 nm diameter monodispersed ammonium sulfate aerosol are measured under different particle concentrations. A cross-section of 1.12 10-8cm2 for ammonium sulfate at 532 nm wavelength is obtained, which agree well with the literature result of 1.167 10-8cm2. The results demonstrate the ability of our system to quantitativly measure aerosol optical properties.-
Keywords:
- incoherent broadband cavity enhanced absorption spectroscopy/
- trace gas detection/
- aerosol extinction
[1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] [15] [16] [17] [18] -
[1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] [15] [16] [17] [18]
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