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    董美丽, 赵卫雄, 程跃, 胡长进, 顾学军, 张为俊

    Incoherent broadband cavity enhanced absorption spectroscopy for trace gases detection and aerosol extinction measurement

    Dong Mei-Li, Zhao Wei-Xiong, Cheng Yue, Hu Chang-Jin, Gu Xue-Jun, Zhang Wei-Jun
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    • 基于氙灯的非相干宽带腔增强吸收光谱系统, 并将其应用于痕量气体及气溶胶消光系数的测量. 该系统的探测灵敏度通过测量NO2在520560 nm波长范围内的吸收得到验证, 最小可探测灵敏度为1.8 10-7cm-1 (1, 0.12 s积分时间, 50次平均), 对应的NO2探测极限~33 nmol/mol. 结合标准气溶胶粒子发生系统, 测量了不同浓度的单分散硫酸铵气溶胶粒子在532 nm波长处的消光系数, 得到粒径为600 nm的硫酸铵气溶胶的消光截面为1.12 10-8cm2, 与文献报道值1.167 10-8cm2相一致, 验证了气溶胶测量的可行性和准确性.
      We report on the development of incoherent broadband cavity enhanced absorption spectroscopy system based on a short arc Xenon lamp for trace gas detection and aerosol optical properties measurements. A minimum detection sensitivity of 1.8 10-7cm-1 (1, 0.12 s integrating time, and 50 times average) is obtained on the basis of absorption spectroscopy of NO2 in a spectral range of 520560 nm, which corresponds to a minimum detection concentration of ~33 nmol/mol for NO2. Combining a laboratory aerosol generation system, the extinction coefficients of 600 nm diameter monodispersed ammonium sulfate aerosol are measured under different particle concentrations. A cross-section of 1.12 10-8cm2 for ammonium sulfate at 532 nm wavelength is obtained, which agree well with the literature result of 1.167 10-8cm2. The results demonstrate the ability of our system to quantitativly measure aerosol optical properties.
          通信作者:张为俊,wjzhang@aiofm.ac.cn
        • 基金项目:国家自然科学基金(批准号:41005017,40975080)、中国科学院知识创新工程重要方向性项目(批准号:KJCX2-YW-N24)和中国科学院合肥物质科学研究院知识创新工程青年人才领域前沿(批准号:O83RC11126)资助的课题.
          Corresponding author:Zhang Wei-Jun,wjzhang@aiofm.ac.cn
        • Funds:Project supported by the National Natural Science Foundation of China (Grant Nos. 41005017, 40975080), the Main Direction Program of Knowledge Innovation of Chinese Academy of Science (Grant No. KJCX2-YW-N24), and the Program of Knowledge Innovation of Hefei Institutes of Physical Science, Chinese Academy of Sciences (Grant No. O83RC11126).
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      出版历程
      • 收稿日期:2011-06-21
      • 修回日期:2011-07-28
      • 刊出日期:2012-03-05

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