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镍基超导体因其具有与铜基高温超导体相似的电子构型而受到广泛关注. 近期, 压力下双层镍氧化物La3Ni2O7中高达80 K的超导转变不仅引发了新一轮镍基超导研究的热潮, 也为非常规超导体的研究开辟了新方向. 层状镍基超导体在结构特征、超导性质以及电子结构方面与铜基、铁基超导体既具有相似性, 也存在显著差异. 对镍基超导体电子结构的深入研究有望揭示这些异同背后的物理机制, 为构建统一的理论模型提供关键依据, 从而推动非常规超导研究的发展. 此外, 非平衡态超快动力学的研究为非常规超导提供了新的视角和调控手段, 并逐渐成为非常规超导研究的重要手段之一. 本文聚焦于Ruddlesden-Popper相层状镍基超导体的电子结构与超快动力学研究, 系统回顾了角分辨光电子能谱和超快光反射率测量在镍基超导研究中的成功应用. 这些研究进展为理解非常规超导机制及其正常态性质提供了重要的实验信息.Nickel-based superconductors have attracted widespread attention due to their electronic configuration similar to that of copper-based high-temperature superconductors. Recently, the discovery of superconductivity with a transition temperature as high as 80 K in the bilayer nickelate La3Ni2O7 under pressure has not only reignited research interest in nickel-based superconductors but also opened new avenues for the study of unconventional superconductivity. Layered nickel-based superconductors are similar to copper- and iron-based superconductors in crystal structure, superconducting properties, and electronic structure, but they also show significant differences. A deeper investigation into the electronic structure of nickel-based superconductors is expected to reveal the mechanisms behind these similarities and differences, which will further offer critical insights into developing a unified theoretical model and deepen the understanding of unconventional superconductivity. Moreover, the study of nonequilibrium ultrafast dynamics offers new perspectives and regulations for unconventional superconductivity, which has become a vital tool. This paper focuses on the electronic structure and ultrafast dynamics of Ruddlesden-Popper phase layered nickel-based superconductors, systematically reviewing the successful applications of angle-resolved photoemission spectroscopy (ARPES) and ultrafast optical spectroscopy in nickel-based superconductivity research. Specifically, the new properties of different nickelates are compared, including strong electron correlation, Hund coupling, non-Fermi liquid behavior, energy gap formation, and ultrafast electron dynamics. These advances offer important experimental insights into elucidating the mechanisms of unconventional superconductivity and characterizing the properties of their normal states in these materials.
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Keywords:
- nickel-based superconductors /
- electronic structure /
- electron-phonon coupling /
- electron correlation /
- ultrafast dynamics
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