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铁电薄膜及其集成的铁电器件受到了极大的关注. 传统铁电薄膜受限于临界尺寸效应, 难以在厚度逐渐变薄至纳米甚至单原子层时保持铁电性, 这为发展相关纳米电子学器件带来了挑战. 二维范德瓦耳斯材料具有天然稳定的层状结构, 具有表面平整无悬挂键、无层间界面陷阱、甚至在原子尺度极限厚度下仍能保持完整的物理化学特性的优点, 逐渐被人们意识到是实现二维铁电性理想的温床. CuInP2S6, α-In2Se3, WTe2等具有本征铁电极化的二维范德瓦耳斯铁电材料先后被报道, 同时人工堆叠的滑移铁电体如t-BN等也逐渐涌现, 极大扩充了二维范德瓦耳斯铁电材料的体系结构, 为进一步实现铁电的电子元器件微型化和柔韧化提供了新的可能. 本文将对近来报道的进行综述, 探讨了它们的组分特征、结构特点及性能调控方法, 并展望此类材料的应用潜力和未来的研究热点.Ferroelectric thin films and their device applications have drawn wide attentions since the 1990s. However, due to the critical size effect, ferroelectric thin films cannot maintain their ferroelectric properties as their thickness decreases to the nanometer size or one atomic layer, posing a significant challenge to the development of related nano-electronic devices. With a naturally stable layered structure, two-dimensional materials possess many advantages such as high-quality and smooth interface without dangling bonds, no interlayer interface defects, and the ability to maintain complete physical and chemical properties even at limited atomic thickness. Thus, it is gradually realized that two-dimensional materials are a good hotbed for the two-dimensional ferroelectricity. CuInP2S6, α-In2Se3, WTe2, and other intrinsic ferroelectric 2D materials have been reported successively while artificially stacked sliding ferroelectrics such as t-BN have also emerged, which expands the types of 2D ferroelectric materials and opens a new avenue for the further miniaturization and flexibility of ferroelectric electronic devices. This article reviews the recent research progress of two-dimensional ferroelectric materials, discusses their compositional characteristics, structural features and property modulation, and also prospects their application potential and future research hotspots.
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Keywords:
- two-dimensional materials /
- ferroelectrics /
- room temperature two-dimensional ferroelectricity /
- ferroelectric devices
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材料 居里温度Tc/K 矫顽场Ec/(kV·cm–1) 剩余极化强度Pr/(μC·cm–2) 压电常数/(pm·V–1) 参考文献 CuInP2S6 ~320 25—30 ~4 d33 = –95 [31,32,60–63] α-In2Se3 473 1000—4000 0.4 d33 = 1.17 [74,92] SnTe 270 — — — [34] MoTe2 >300 — — — [79] WTe2 350 — 0.051 — [93] β-InSe >300 1500 0.375 — [94,95] GaSe >350 — 0.0619 d11 = 2.3 [96,97] SnS >300 — 0.018—0.048 d33 = 2.2 [98,99] 3R-MoS2 >650 1000—1900 ~0.02 d33 = 2.09 [100,101] Twisted BN 620 3000 0.68 d33 = 0.5 [102] Sc2CO2 300—600 2500 1.6 — [103,104] Bi2O2Se 508 ~8000 — 4.4 [87,105] NbOI2 ~462.42 ~8.5 1.43 0.6 [88] -
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