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Abstract

The red-brown CdSe thin films are electrochemically deposited on conductive ITO/TiO2 film surfaces, and the multilayer TiO2/CdSe structures are constructed. The microstructures and the photoelectrochemical properties of multilayer TiO2/CdSe structures are investigated. The results show that the CdSe thin films are grown preferentially along the (111) direction. The thickness and UV-Vis absorbance intensity of multilayer films increase with the increase of layer number of TiO2/CdSe structure. The results obtained from photoelectrochemistry measurement indicate that the optimal photoelectrochemical current response and open-circuit voltage are obtained in a biolayer TiO2/CdSe system, which therefore demonstrates the favorable photoelectrochemical properties.

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Funds:Project supported by the National Natural Science Foundation of China (Grant Nos. 50902123, 51172208, 60806045), the Visiting Scholars Fund of State Key Laboratory of Silicon Materials, China (Grant No. SKL2011-20), the Excellent Young Talents Foundation of Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-Tech University), China (Grant No. 2011QN05), the Qianjiang Talent Program of Zhejiang Province, China (Grant No. QJD1102007), the Education and Teaching Research Program of Zhejiang Sci-Tech University, China (Grant No. el1107), and the Scientific Research Foundation of Zhejiang Sci-Tech University, China (Grant No. 0813824-Y).

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Vol. 61, Issue 10 - 2012-05-20

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