- 必威体育下载

姓名
邮箱
手机号码
标题
留言内容
验证码

Abstract

The resonance Raman spectra of nonpolar molecule all-trans--carotene and polar molecule canthaxanthin in nonpolar CS2 and polar 1,2-dicholoroethane in a temperature range from 243K to 293K are measured. The results show that polarities of the solute and solvent have a great effect on Raman spectrum. Raman scattering cross-section of nonpolar all-trans--carotene in nonpolar solvent CS2 is biggest and its bandwidth is narrowest. Raman scattering cross-section of polar canthaxanthin in polar solvent 1,2-dicholoroethane is smallest and its bandwidth is widest. The experimental phenomena are explained by solvent effects, coherent weakly damped electron-lattice vibration and effective conjugated length.

Keywords:

Authors and contacts

1.
2.
Funds:Project supported by the National Natural Science Foundation of China (Grant No. 10974067), Program for New Century Excellent Talents in University, China (Grant No. NCET-11-0201) and Innovative Research Team of Jilin Province, China (Grant N0. 20121806).

References

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]
[28]
[29]
[30]
[31]

Cited By

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]
[28]
[29]
[30]
[31]

[1]	Shen Huan, Hua Lin-Qiang, Wei Zheng-Rong.Solvent effect on ultrafast decay of uracil studied by femtosecond transient absorption spectroscopy. Acta Physica Sinica, 2022, 71(18): 184206.doi:10.7498/aps.71.20220515
[2]	Meng Da, Cong Xin, Leng Yu-Chen, Lin Miao-Ling, Wang Jia-Hong, Yu Bin-Lu, Liu Xue-Lu, Yu Xue-Feng, Tan Ping-Heng.Resonant Multi-phonon Raman scattering of black phosphorus. Acta Physica Sinica, 2020, 69(16): 167803.doi:10.7498/aps.69.20200696
[3]	Zhang Lai-Bin, Ren Ting-Qi.Theoretical study on the photophysical properties of the newly designed guanine analog y-guanine and its tautomers. Acta Physica Sinica, 2015, 64(7): 077101.doi:10.7498/aps.64.077101
[4]	Xu Sheng-Nan, Liu Tian-Yuan, Sun Mei-Jiao, Li Shuo, Fang Wen-Hui, Sun Cheng-Lin, Li Zuo-Wei.Solvent effects on the electron-vibration coupling constant of β-carotene. Acta Physica Sinica, 2014, 63(16): 167801.doi:10.7498/aps.63.167801
[5]	Han Dong, Chen Liang-Fu, Li Shen-Shen, Tao Jin-Hua, Su Lin, Zou Ming-Min, Fan Meng.A convolution algorithm of differential coefficients of liquid water based on vibrational Raman scattering. Acta Physica Sinica, 2013, 62(10): 109301.doi:10.7498/aps.62.109301
[6]	Xue Si-Min.A theoretical study on non-first-order effects of double differential cross sections. Acta Physica Sinica, 2013, 62(16): 163401.doi:10.7498/aps.62.163401
[7]	Qu Guan-Nan, Li Shuo, Sun Mei-Jiao, Xu Sheng-Nan, Liu Yu, Sun Cheng-Lin, Men Zhi-Wei, Li Zuo-Wei.Temperature effects on structural order of all-trans-β-carotene. Acta Physica Sinica, 2013, 62(7): 077801.doi:10.7498/aps.62.077801
[8]	Huang Qian, Xiong Shao-Zhen, Zhao Ying, Zhang Xiao-Dan.Nonlinear phenomenon of surface enhanced Raman scattering caused by surface plasmon. Acta Physica Sinica, 2012, 61(15): 157801.doi:10.7498/aps.61.157801
[9]	Zhao Ke, Liu Peng-Wei, Han Guang-Chao.Applications of molecular dynamics simulation in nonlinear optics. Acta Physica Sinica, 2011, 60(12): 124216.doi:10.7498/aps.60.124216
[10]	Li Zhan-Long, Zhou Mi, He Li-Qiao, Sun Cheng-Lin, Li Zuo-Wei, Men Zhi-Wei.Enhanced stimulated Raman scattering of binary solution by intermolecular Fermi resonance. Acta Physica Sinica, 2011, 60(9): 094217.doi:10.7498/aps.60.094217
[11]	Li Wen-Feng, Linghu Rong-Feng, Cheng Xin-Lu, Yang Xiang-Dong.Theoretical calculation of integral cross sections of rotational excitation for collisions in isotopes of He atom with Na2 molecule. Acta Physica Sinica, 2010, 59(7): 4591-4597.doi:10.7498/aps.59.4591
[12]	Wang Xiao-Lian, Feng Hao, Sun Wei-Guo, Fan Qun-Chao, Zeng Yang-Yang, Wang Bin.Momentum transfer cross sections of low-energy electron scattering from H2 molecule. Acta Physica Sinica, 2010, 59(2): 937-942.doi:10.7498/aps.59.937
[13]	Linghu Rong-Feng, Li Jin, Si Guan-Jie, Yang Xiang-Dong.Theoretical calculation of the low-energy scattering cross sections for He-Li2 system. Acta Physica Sinica, 2010, 59(8): 5424-5428.doi:10.7498/aps.59.5424
[14]	Li Ming-Xue, Han Kui, Li Hai-Peng, Huang Zhi-Min, Zhong Qi, Tong Xing, Wu Qiong-Hua.Theoretical study of the second-order nonlinear optical properties of one- and two-dimensional charge transfer molecules in solvents. Acta Physica Sinica, 2010, 59(3): 1809-1815.doi:10.7498/aps.59.1809
[15]	Zhu Jing, Lü Chang-Gui, Hong Xu-Sheng, Cui Yi-Ping.Theoretical study on solvent effect of the molecular first hyperpolarizability. Acta Physica Sinica, 2010, 59(4): 2850-2854.doi:10.7498/aps.59.2850
[16]	Qu Guan-Nan, Li Dong-Fei, Li Zhan-Long, Ouyang Shun-Li, Li Zuo-Wei, Gao Shu-Qin, Zhou Mi, Men Zhi-Wei, Wang Wei-Wei, Yang Jian-Ge.The influence of solvent density to Raman scattering cross-section of β-carotene. Acta Physica Sinica, 2010, 59(5): 3168-3172.doi:10.7498/aps.59.3168
[17]	Wang Bin, Feng Hao, Sun Wei-Guo, Zeng Yang-Yang, Dai Wei.Vibrational excitation integrated cross sections of e-H2 scattering. Acta Physica Sinica, 2009, 58(10): 6932-6937.doi:10.7498/aps.58.6932
[18]	Cao Biao, Zuo Jian, Li Zuo-Wei, Ouyang Shun-Li, Gao Shu-Qin, Lu Guo-Hui, Jiang Yong-Heng.Amendment to bertran equation and the weak Fermi resonance characteristic of CS2 in C6H6. Acta Physica Sinica, 2009, 58(5): 3538-3542.doi:10.7498/aps.58.3538
[19]	Li Zhan-Long, Ouyang Shun-Li, Cao Biao, Zhou Mi, Li Zuo-Wei, Gao Shu-Qin.Effect of solvent refractive index on Raman cross-section of β-carotene. Acta Physica Sinica, 2009, 58(10): 6908-6912.doi:10.7498/aps.58.6908
[20]	Han Qing-Zhen, Geng Chun-Yu, Zhao Yue-Hong, Qi Chuan-Song, Wen Hao.The solvent effects on the complexing reaction of nickel dithiolene and ethylene. Acta Physica Sinica, 2008, 57(1): 96-102.doi:10.7498/aps.57.96

Catalog

Vol. 62, Issue 3 - 2013-02-05

Metrics

Abstract views:7195
PDF Downloads:960
Cited By:0

Search

Article

留言板

Abstract

Authors and contacts

References

Cited By

Catalog

Metrics

Authors

Referees

About Journal

About

Search

Article

留言板

Abstract

Authors and contacts

References

Cited By

Catalog

Metrics

Publishing process

Authors

Referees

About Journal

About