In this paper, backstepping and adaptive dynamical sliding mode control is used to achieve chaos synchronization of coupled FitzHugh-Nagumo (FHN) neurons. The proposed controller consists of a combination of dynamical sliding mode control and adaptive backstepping technique. Based on a new switching function, the combined algorithm yields a design of dynamical sliding mode control law, which can realize chaos synchronization of coupled FHN neurons with uncertain parameters. It is shown that the proposed approach can effectively remove the chattering characteristic of the system, so that the intrinsic dynamics of neurons can avoid to be destroyed. Furthermore, it has rapid control performance. The simulation results have demonstrated the effectiveness of the control scheme.