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Abstract

have been recorded in the spectral range 101600 cm-1 at room temperature. Factor group analysis was used to obtain the normal modes of vibration of the crystal. The Raman peaks under 300 cm-1 are assigned to external modes, which are related to the rotational and transitional movement of the [BiO6], [ZnO4], [BO4] and [BO3] groups. Compared with the vibrational spectra of the compounds referred, the satisfactory assignment of most of the high-energy modes to vibrations of Bi-O, B-O and Zn-O bonds can be achieved. In particular, the Raman high-frequency peak located at 1407 cm-1 is attributed to the B-O vibration in the [BO3] triangle.

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Funds:Project supported by the National Natural Science Foundation of China (Grant Nos. 50932005, 51102239, 90922003, 51172236, 91122021) and the Natural Science Foundation of Anhui Provence, China (Grant No. KJ2013B106).

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Vol. 62, Issue 23 - 2013-12-05

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