Zhang Xiao-Chun; Wang Li-Kun; Shang Wen-Li; Wan Zheng-Hui; Yue Xin; Yang Hua-Yi; Li Ting; Wang Hui

doi:10.7498/aps.73.20241238

Abstract

Inverted (p-i-n) perovskite solar cells (PSCs) are receiving increasing attention due to their high conversion efficiency and good stability. The main factor restricting the efficiency improvement of inverted perovskite cells is the interface defect between the perovskite layer and the charge transport layers. Therefore, the dual modification strategy of 1, 3-diaminopropane dihydroiodide (PDADI) passivates the interface defects between perovskite films and charge transport layers, improves the quality of perovskite film formation, suppresses non radiative recombination between perovskite films and charge transport layers as well as improved charge carrier transport, and results in a conversion efficiency of 23.19%. Furthermore, the unencapsulated PSCs with PDADI dual modification also exhibit good storage stability, with efficiency remaining at 96% of initial efficiency after 600 hours of storage at a temperature of 25 ℃ and humidity below 20%. Therefore, PDADI dual modification provides an effective strategy for fabricating high-efficiency and stable inverted perovskite solar cells.

Keywords:

Authors and contacts

Corresponding author: Li Ting, tingli430@lnnu.edu.cn ; Wang Hui, hwang1606@dicp.ac.cn

Funds: Project supported by the Doctor Foundation of Science and Technology Department of Liaoning Province, China (Grant No. 2021-BS-200).

FullText HTML : translate this paragraph

References

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]

Cited By

DownLoad: Full-Size Img PowerPoint

	T₁/ns	A₁	T₂/ns	A₂	T_average/ns
Control	149.17	23.40	2089.05	1.16	311.27
Single-modification	228.55	14.99	1528.54	0.82	295.77
Dual-modification	183.4	28.71	991.57	1.37	220.21

DownLoad: CSV

		V_oc/V	J_sc/(mA·cm^–2)	Fill factor/%	Efficiency/%
Control	Forward	1.02	25.04	73.02	18.80
Control	Reverse	1.04	25.16	81.19	21.34
Single-modification	Forward	1.05	25.19	77.99	20.81
Single-modification	Reverse	1.06	25.24	82.89	22.27
Dual-modification	Forward	1.09	25.34	82.25	22.55
Dual-modification	Reverse	1.09	25.36	84.15	23.19

DownLoad: CSV

map

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]

[1]	Juan Ting, Xing Jia-He, Zeng Fan-Cong, Zheng Xin, Xu Lin. Performance of perovskite solar cells based on SnO₂:DPEPO hybrid electron transport layer. Acta Physica Sinica, 2024, 73(19): 198401. doi: 10.7498/aps.73.20240827
[2]	Liu Si-Wen, Ren Li-Zhi, Jin Bo-Wen, Song Xin, Wu Cong-Cong. Preparation of two-dimensional perovskite layer by solution method for improving stability of FAPbI₃ perovskite solar cells. Acta Physica Sinica, 2024, 73(6): 068801. doi: 10.7498/aps.73.20231678
[3]	Jin Cheng-Cheng, Ding Ling-Ling, Song Zi-Xin, Tao Hai-Jun. Improvement of performance of perovskite solar cells through BaTiO₃ doping regulated built-in electric field. Acta Physica Sinica, 2024, 73(3): 038801. doi: 10.7498/aps.73.20231139
[4]	Wang Jing, Gao Shan, Duan Xiang-Mei, Yin Wan-Jian. Influence of defect in perovskite solar cell materials on device performance and stability. Acta Physica Sinica, 2024, 73(6): 063101. doi: 10.7498/aps.73.20231631
[5]	Wang Hui, Zheng De-Xu, Jiang Xiao, Cao Yue-Xian, Du Min-Yong, Wang Kai, Liu Sheng-Zhong, Zhang Chun-Fu. Fabrication of high-performance flexible perovskite solar cells based on synergistic passivation strategy. Acta Physica Sinica, 2024, 73(7): 078401. doi: 10.7498/aps.73.20231846
[6]	Li Pei, Xu Jie, He Chao-Hui, Liu Jia-Xin. Experimental study on irradiation of perovskite solar cells. Acta Physica Sinica, 2023, 72(12): 126101. doi: 10.7498/aps.72.20230230
[7]	Zhu Yong-Qi, Liu Yu-Xue, Shi Yang, Wu Cong-Cong. High performance perovskite solar cells synthesized by dissolving FAPbI₃ single crystal. Acta Physica Sinica, 2023, 72(1): 018801. doi: 10.7498/aps.72.20221461
[8]	Xue Bin-Tao, Zhang Li-Min, Liang Yong-Qi, Liu Ning, Wang Ding-Ping, Chen Liang, Wang Tie-Shan. Proton irradiation induced damage effects in CH₃NH₃PbI₃-based perovskite solar cells. Acta Physica Sinica, 2023, 72(13): 138802. doi: 10.7498/aps.72.20222100
[9]	Yang Mei-Li, Zou Li, Cheng Jia-Jie, Wang Jia-Ming, Jiang Yu-Fan, Hao Hui-Ying, Xing Jie, Liu Hao, Fan Zhen-Jun, Dong Jing-Jing. Improvement of performance of CsPbBr₃ perovskite solar cells by polyvinylidene fluoride additive. Acta Physica Sinica, 2023, 72(16): 168101. doi: 10.7498/aps.72.20230636
[10]	Zhou Yang, Ren Xin-Gang, Yan Ye-Qiang, Ren Hao, Du Hong-Mei, Cai Xue-Yuan, Huang Zhi-Xiang. Physical mechanism of perovskite solar cell based on double electron transport layer. Acta Physica Sinica, 2022, 71(20): 208802. doi: 10.7498/aps.71.20220725
[11]	Sui Guo-Min, Yan Gui-Jun, Yang Guang, Zhang Bao, Feng Ya-Qing. Theoretical investigation on structure and optoelectronic performance of two-dimensional fluorbenzidine perovskites. Acta Physica Sinica, 2022, 71(20): 208801. doi: 10.7498/aps.71.20220802
[12]	Zhong Ting-Ting, Zhang Chen, Shindume Lomboleni Hamukwaya, Xu Wang-Shu, Tang Kun-Peng, Xu Xiang, Sun Wen-Tian, Hao Hui-Ying, Dong Jing-Jing, Liu Hao, Xing Jie. Efficient and stable carbon-based CsPbBr₃ solar cells added with PEABr additive. Acta Physica Sinica, 2022, 71(2): 028101. doi: 10.7498/aps.71.20211344
[13]	Liu Yu-Xue, Ming Yi-Dong, Wu Cong-Cong. Properties and improvements of chlorine-doped methylamine-based perovskites. Acta Physica Sinica, 2022, 71(20): 207303. doi: 10.7498/aps.71.20220966
[14]	Wang Cheng-Lin, Zhang Zuo-Lin, Zhu Yun-Fei, Zhao Xue-Fan, Song Hong-Wei, Chen Cong. Progress of defect and defect passivation in perovskite solar cells. Acta Physica Sinica, 2022, 71(16): 166801. doi: 10.7498/aps.71.20220359
[15]	Wang Pei-Pei, Zhang Chen-Xi, Hu Li-Na, Li Shi-Qi, Ren Wei-Hua, Hao Yu-Ying. Research progress of inverted planar perovskite solar cells based on nickel oxide as hole transport layer. Acta Physica Sinica, 2021, 70(11): 118801. doi: 10.7498/aps.70.20201896
[16]	. Adopting PEABr additive to obtain efficient and stable carbon-based CsPbBr3 solar cells. Acta Physica Sinica, 2021, (): . doi: 10.7498/aps.70.20211344
[17]	Gao Jiu-Lin, Lian Ya-Jun, Yang Ye, Li Guo-Qing, Yang Xiao-Hui. High-efficiency sky blue perovskite light-emitting diodes with ammonium thiocyanate additive. Acta Physica Sinica, 2021, 70(19): 198502. doi: 10.7498/aps.70.20211046
[18]	Li Xiao-Guo, Zhang Xin, Shi Ze-Jiao, Zhang Hai-Juan, Zhu Cheng-Jun, Zhan Yi-Qiang. Research progress of interface passivation of n-i-p perovskite solar cells. Acta Physica Sinica, 2019, 68(15): 158803. doi: 10.7498/aps.68.20190468
[19]	Chai Lei, Zhong Min. Recent research progress in perovskite solar cells. Acta Physica Sinica, 2016, 65(23): 237902. doi: 10.7498/aps.65.237902
[20]	Ting Hung-Kit, Ni Lu, Ma Sheng-Bo, Ma Ying-Zhuang, Xiao Li-Xin, Chen Zhi-Jian. progress in electron-transport materials in application of perovskite solar cells. Acta Physica Sinica, 2015, 64(3): 038802. doi: 10.7498/aps.64.038802

Catalog

Vol. 73, Issue 24 - 2024-12-20

Metrics

Abstract views: 397
PDF Downloads: 21
Cited By: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

Search

Article

留言板

Abstract

Authors and contacts

Corresponding author: Li Ting, tingli430@lnnu.edu.cn ; Wang Hui, hwang1606@dicp.ac.cn

FullText HTML : translate this paragraph

References

Cited By

Catalog

Metrics

Authors

Referees

About Journal

About

Search

Article

留言板

Abstract

Authors and contacts

Corresponding author: Li Ting, tingli430@lnnu.edu.cn ; Wang Hui, hwang1606@dicp.ac.cn

FullText HTML : translate this paragraph

References

Cited By

Catalog

Metrics

Publishing process

Authors

Referees

About Journal

About