With the advancement of synchrotron and free-electron laser, X-ray quantum optics has emerged as a novel frontier for exploring light-matter interactions at high photon energies. A significant challenge in this field is achieving well-defined two-level systems through atomic inner-shell transitions, which are often hindered by broad natural linewidths and their overlap with the ionization continuum. This study aims to explore the potential of tungsten disilicide (WSi₂) as a two-level system for X-ray quantum optics applications. Utilizing high-resolution resonant inelastic X-ray scattering (RIXS) near the W-L₃ edge, In this work, the pre-edge white line is experimentally distinguished from the ionization continuum, overcoming the spectral broadening caused by short core-hole lifetime. The measurements are conducted by using a von Hamos spectrometer at the GALAXIES beamline of the SOLEIL synchrotron. The results reveal a single resonant emission feature with a fixed energy transfer, confirming the presence of a discrete 2p–5d transition characteristic of a two-level system. Additional high-resolution XAS spectra, obtained via high energy resolution fluorescence detection method and reconstructed from off-resonant emission method, further support the identification of a sharp white line. These findings demonstrate the feasibility of using WSi₂ as a model system in X-ray cavity quantum optics and establish RIXS as a powerful technique to resolve fine inner-shell structures.